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Tunable Slow Dynamics in a New Class of Soft Colloids

机译:一类新型软胶体的可调谐慢动力学

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摘要

By means of extensive simulations, we investigate concentrated solutions ofglobular single-chain nanoparticles (SCNPs), an emergent class of syntheticsoft nano-objects. By increasing the concentration, the SCNPs show a reentrantbehaviour in their structural and dynamical correlations, as well as a softcaging regime and weak dynamic heterogeneity. The latter is confirmed byvalidation of the Stokes-Einstein relation up to concentrations far beyond theoverlap density. Therefore SCNPs arise as a new class of soft colloids,exhibiting slow dynamics and actualizing in a real system structural anddynamical anomalies proposed by models of ultrasoft particles. Quantitativedifferences in the dynamical behaviour depend on the SCNP deformability, whichcan be tuned through the degree of internal cross-linking.
机译:通过广泛的模拟,我们研究了球形单链纳米颗粒(SCNP)的浓缩溶液,这是一类新兴的合成软纳米物体。通过增加浓度,SCNPs在其结构和动力学相关性方面表现出可重入的行为,并且具有软笼机制和弱的动态异质性。后者通过对斯托克斯-爱因斯坦关系的验证而得到证实,直至浓度远超过重叠密度。因此,SCNPs作为一类新的软胶体出现,表现出缓慢的动力学,并在超软颗粒模型提出的真实系统中实现结构和动力学异常。动力学行为的数量差异取决于SCNP的可变形性,可通过内部交联的程度对其进行调整。

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